50 MCQ on Chemical Bonding with option and answer with explanation

1 . What is the name given to the bond between two atoms that share electrons?

A . Ionic bond

B .Covalent bond

C . Metallic bond

D . Hydrogen bond

Answer: b. Covalent bond.

 Explanation: In a covalent bond, two atoms share a pair of electrons to complete their outermost energy level.

2 . Which of the following is not a type of chemical bond?

A . Ionic bond

B . Covalent bond

C . Metallic bond

D . Electronegative bond

Answer: d. Electronegative bond.

Explanation: Electronegativity is a property of atoms that determines the polarity of a covalent bond.

3 . Which of the following is not a characteristic of an ionic bond?

A . High melting and boiling points

B . Solubility in water

C . Brittle nature

D . Low electrical conductivity

Answer: d. Low electrical conductivity.

 Explanation: Ionic compounds conduct electricity when dissolved in water or molten state.

4 .In which type of bond do two atoms share one electron each?

A . Single covalent bond

B . Double covalent bond

C . Triple covalent bond

D . Polar covalent bond

Answer: a. Single covalent bond.

Explanation: A single covalent bond is formed when two atoms share one electron each to complete their outermost energy level.

5 . Which of the following statements is true about a polar covalent bond?

A . The electrons are equally shared between the two atoms.

B . The electrons are not shared between the two atoms.

C . The electrons are shared unequally between the two atoms.

D . The bond is formed between a metal and a non-metal.

Answer: c. The electrons are shared unequally between the two atoms.

Explanation: In a polar covalent bond, the electrons are shared unequally between the two atoms, resulting in a partial positive and partial negative charge.

6 .Which of the following is a characteristic of a metallic bond?

a . Sharing of electrons between two atoms

b . Transfer of electrons from one atom to another

c . Presence of delocalized electrons

d . Formation of ions

Answer: c. Presence of delocalized electrons.

 Explanation: In a metallic bond, valence electrons are delocalized and shared among all the atoms in the metal.

7 . Which of the following is a characteristic of a covalent bond?

a . Transfer of electrons from one atom to another

b . Formation of ions

c . Sharing of electrons between two atoms

d . Presence of delocalized electrons

Answer: c. Sharing of electrons between two atoms.

Explanation: In a covalent bond, two atoms share electrons to complete their outermost energy level.

8 . Which of the following bonds is the strongest?

a . Covalent bond

b . Ionic bond

c . Metallic bond

d . Hydrogen bond

Answer: b. Ionic bond.

Explanation: Ionic bonds involve the transfer of electrons from one atom to another, resulting in the formation of ions, which are held together by strong electrostatic forces.

9 . Which of the following elements has the highest electronegativity?

a . Sodium

b . Chlorine

c . Carbon

d . Oxygen

Answer: d. Oxygen.

 Explanation: Electronegativity is a measure of an atom’s ability to attract electrons in a covalent bond. Oxygen has the highest electronegativity value among the given options.

10 . Which of the following elements is least likely to form an ionic bond?

a . Sodium

b . Carbon

c . Chlorine

d . Potassium

Answer: b. Carbon.

 Explanation: Carbon has four valence electrons, which it can share to form covalent bonds. It is less likely to lose or gain electrons to form ions, unlike sodium, chlorine, and potassium.

11 . Which of the following elements is most likely to form an ionic bond?

a . Nitrogen

b . Fluorine

c . Sodium

d . Oxygen

Answer: c. Sodium.

 Explanation: Sodium has one valence electron, which it can lose to form a cation with a positive charge. This cation can then bond with an anion, such as chlorine, to form an ionic bond.

12 . What is the bond angle in a molecule of water (H2O)?

a . 90 degrees

b . 120 degrees

c . 180 degrees

d . 104.5 degrees

Answer: d. 104.5 degrees.

 Explanation: The molecule of water has a bent shape due to the presence of two lone pairs of electrons on the central oxygen atom. This results in a bond angle of 104.5 degrees.

13 . Which of the following is a non-polar molecule?

a . HCl

b . NH3

c . CO2

d . H2O

Answer: c. CO2.

 Explanation: CO2 is a linear molecule with two polar covalent bonds between the carbon and oxygen atoms. However, the polarities of the two bonds cancel out, resulting in a non-polar molecule.

14 . What is the bond order of a triple covalent bond?

a . 1

b . 2

c . 3

d . 4

Answer: c. 3.

Explanation: The bond order is the number of bonds between two atoms in a molecule. A triple covalent bond consists of three shared pairs of electrons between two atoms, resulting in a bond order of 3.

15 . What is the shape of a molecule with a tetrahedral electron geometry?

a . Linear

b . Trigonal planar

c . Tetrahedral

d . Octahedral

Answer: c. Tetrahedral.

 Explanation: A tetrahedral electron geometry consists of four electron pairs arranged around a central atom in a three-dimensional tetrahedral shape.

16 . Which of the following molecules has a linear shape?

a . CO2

b . NH3

c . H2O

d . CH4

Answer: a. CO2.

Explanation: CO2 is a linear molecule with a bond angle of 180 degrees due to the presence of two double bonds between the carbon and oxygen atoms.

17 . Which of the following is not a factor that affects the strength of an ionic bond?

a . Size of the ions

b . Charge of the ions

c . Electronegativity of the ions

d . Type of element

Answer: d. Type of element.

 Explanation: The strength of an ionic bond is primarily determined by the size and charge of the ions and their electronegativity values.

18 . Which of the following is not a type of intermolecular force?

a . Hydrogen bonding

b . London dispersion forces

c . Covalent bonding

d . Dipole-dipole interactions

Answer: c. Covalent bonding.

Explanation: Covalent bonding refers to the sharing of electrons between two atoms to form a molecule. Intermolecular forces refer to the forces of attraction between molecules.

19 . Which of the following statements is true about metallic bonding?

a . Electrons are transferred from one atom to another.

b . Electrons are shared equally between two atoms.

c . Valence electrons are free to move throughout the metal lattice.

d . Metallic bonds are weak compared to other types of bonds.

Answer: c. Valence electrons are free to move throughout the metal lattice.

 Explanation: In metallic bonding, valence electrons are delocalized and free to move throughout the metal lattice. This creates a sea of electrons that holds the metal atoms together.

20 . Which of the following statements is true about covalent bonds?

a . Covalent bonds are stronger than ionic bonds.

b . Covalent bonds are formed between metals and nonmetals.

c . Covalent bonds involve the transfer of electrons.

d . Covalent bonds involve the sharing of electrons.

Answer: d. Covalent bonds involve the sharing of electrons.

Explanation: Covalent bonds are formed when two atoms share one or more pairs of electrons. They are typically formed between non-metallic elements and can be either polar or nonpolar.

21 . Which of the following molecules has a polar covalent bond?

a . H2

b . O2

c . Cl2

d . HCl

Answer: d. HCl.

 Explanation: HCl has a polar covalent bond due to the electronegativity difference between hydrogen and chlorine. The chlorine atom is more electronegative than the hydrogen atom, so it attracts the shared electrons more strongly.

22 . Which of the following statements is true about nonpolar molecules?

a . Nonpolar molecules have a net dipole moment.

b . Nonpolar molecules have partial charges.

c . Nonpolar molecules do not interact with other nonpolar molecules.

d . Nonpolar molecules have a symmetrical distribution of electrons.

Answer: d. Nonpolar molecules have a symmetrical distribution of electrons.

 Explanation: Nonpolar molecules have an even distribution of electrons, which results in no net dipole moment. This makes them less likely to interact with polar molecules.

23 . What is the hybridization of the central atom in a molecule with trigonal bipyramidal electron geometry?

a . sp

b . sp2

c . sp3

d . sp3d

Answer: d. sp3d.

 Explanation: A molecule with trigonal bipyramidal electron geometry has five electron pairs around the central atom, which requires sp3d hybridization of the central atom’s orbitals.

24 . What is the hybridization of the central atom in a molecule with octahedral electron geometry?

a . sp

b . sp2

c . sp3

d . d2sp3

Answer: d. d2sp3.

 Explanation: A molecule with octahedral electron geometry has six electron pairs around the central atom, which requires d2sp3 hybridization of the central atom’s orbitals.

25 . What is the hybridization of the central atom in a molecule with linear electron geometry?

a . sp

b . sp2

c . sp3

d . sp3d2

Answer: a. sp.

 Explanation: A molecule with linear electron geometry has two electron pairs around the central atom, which requires sp hybridization of the central atom’s orbitals.

26 . Which of the following is not a valid Lewis structure?

a . H-O-H

b . H-C≡C-H

c . Cl-O-Cl

d . N≡N

Answer: c. Cl-O-Cl.

Explanation: Cl-O-Cl violates the octet rule for both chlorine atoms, as each only has six electrons in its valence shell.

27 . Which of the following molecules has a resonance structure?

a . H2O

b . CO2

c . NO2-

d . CH4

Answer: c. NO2-.

Explanation: NO2- has a resonance structure due to the delocalization of the negative charge between the two oxygen atoms.

28 . Which of the following is the correct order of increasing bond length?

a . C=C < C-C < C≡C

b . C≡C < C-C < C=C

c . C-C < C=C < C≡C

d . C=C < C≡C < C-C

Answer: d. C=C < C≡C < C-C.

Explanation: Triple bonds are shorter than double bonds, which are shorter than single bonds, so the correct order of increasing bond length is C=C < C≡C < C-C.

29 . Which of the following is the correct order of increasing bond strength?

a . C-C < C=C < C≡C

b . C=C < C-C < C≡C

c . C≡C < C-C < C=C

d . C-C < C≡C < C=C

Answer: c. C≡C < C=C < C-C.

 Explanation: Triple bonds are stronger than double bonds, which are stronger than single bonds, so the correct order of increasing bond strength is C≡C < C=C < C-C.

30 . Which of the following molecules has a bond angle of 109.5°?

a . H2O

b . NH3

c . CH4

d . BF3

Answer: c. CH4.

Explanation: CH4 has a tetrahedral electron geometry and a bond angle of 109.5°.

31 . Which of the following molecules has a bond angle of 120°?

a . NH3

b . H2O

c . BF3

d . CO2

Answer: c. BF3.

Explanation: BF3 has a trigonal planar electron geometry and a bond angle of 120°.

32 . Which of the following statements is true about hydrogen bonding?

a . Hydrogen bonding only occurs in molecules that contain hydrogen.

b . Hydrogen bonding is a type of covalent bond.

c . Hydrogen bonding is a type of intermolecular force.

d . Hydrogen bonding is the strongest type of chemical bond.

Answer: c. Hydrogen bonding is a type of intermolecular force.

 Explanation: Hydrogen bonding is a type of intermolecular force that occurs when a hydrogen atom is bonded to a highly electronegative atom, such as nitrogen, oxygen, or fluorine. It is not a type of covalent bond, and it is not the strongest type of chemical bond.

33 . Which of the following substances exhibits hydrogen bonding?

a . H2O

b . CO2

c . CH4

d . NH3

Answer: a. H2O.

 Explanation: H2O exhibits hydrogen bonding because it contains hydrogen atoms bonded to highly electronegative oxygen atoms, and the resulting hydrogen bonds between water molecules give water many of its unique physical properties.

34 . Which of the following statements is true about dipole-dipole forces?

a . Dipole-dipole forces only occur in nonpolar molecules.

b . Dipole-dipole forces are always stronger than London dispersion forces.

c . Dipole-dipole forces are a type of covalent bond.

d . Dipole-dipole forces are a type of intermolecular force that arises from the partial charges on polar molecules.

Answer: d. Dipole-dipole forces are a type of intermolecular force that arises from the partial charges on polar molecules.

Explanation: Dipole-dipole forces are a type of intermolecular force that occurs between polar molecules that have a permanent dipole moment, resulting from the partial charges on the molecule’s atoms. They are not a type of covalent bond and are not present in nonpolar molecules.

35 . Which of the following statements is true about ion-dipole forces?

a . Ion-dipole forces only occur in ionic compounds.

b . Ion-dipole forces are always stronger than ion-ion forces.

c . Ion-dipole forces are a type of covalent bond.

d . Ion-dipole forces are a type of intermolecular force that arises from the attraction between an ion and a polar molecule.

Answer: d. Ion-dipole forces are a type of intermolecular force that arises from the attraction between an ion and a polar molecule.

Explanation: Ion-dipole forces are a type of intermolecular force that occurs when an ion interacts with a polar molecule. This can happen in mixtures of ionic compounds and polar solvents, where the ions can dissolve in the solvent and form ion-dipole interactions with the solvent molecules. They are not a type of covalent bond, and they can be stronger or weaker than ion-ion forces depending on the specific ions and molecules involved.

36 . Which of the following statements is true about metallic bonding?

a . Metallic bonding occurs between atoms of nonmetals.

b . Metallic bonding is a type of covalent bond.

c . Metallic bonding involves the sharing of electrons between atoms.

d . Metallic bonding is the bonding between metal ions and delocalized electrons.

Answer: d. Metallic bonding is the bonding between metal ions and delocalized electrons.

Explanation: Metallic bonding occurs in metals, where the valence electrons of the metal atoms become delocalized and form a “sea” of electrons that are free to move throughout the material. The metal atoms become positively charged metal ions, and the delocalized electrons are attracted to them, creating a strong bond.

37 . Which of the following substances would be expected to have the highest melting point?

a . NaCl

b . CO2

c . CH4

d . H2O

Answer: a. NaCl.

 Explanation: NaCl, or table salt, has the highest melting point of these substances because it has ionic bonds, which are typically stronger than the covalent bonds found in the other substances listed.

38 . Which of the following statements is true about van der Waals forces?

a . Van der Waals forces only occur between nonpolar molecules.

b . Van der Waals forces are stronger than covalent bonds.

c . Van der Waals forces are a type of intermolecular force that includes London dispersion forces and dipole-dipole forces.

d . Van der Waals forces are a type of chemical bond.

Answer: c. Van der Waals forces are a type of intermolecular force that includes London dispersion forces and dipole-dipole forces.

 Explanation: Van der Waals forces are a type of intermolecular force that encompasses all the attractive forces that exist between molecules, including London dispersion forces and dipole-dipole forces. They are not a type of chemical bond, and they can occur between both polar and nonpolar molecules.

39 . Which of the following molecules has a linear molecular geometry?

a .  H2O

b . NH3

c . CO2

d . CH4

Answer: c. CO2.

Explanation: CO2 has a linear molecular geometry because the two oxygen atoms are on opposite sides of the carbon atom and are bonded to it through double bonds, resulting in a linear shape.

40 . Which of the following statements is true about polar covalent bonds?

a . Polar covalent bonds occur between atoms of the same element.

b . Polar covalent bonds involve the sharing of electrons equally between two atoms.

c . Polar covalent bonds involve the unequal sharing of electrons between two atoms.

d . Polar covalent bonds do not contribute to the polarity of a molecule.

Answer: c. Polar covalent bonds involve the unequal sharing of electrons between two atoms.

Explanation: Polar covalent bonds occur when two atoms share electrons unequally due to differences in electronegativity, resulting in a partial positive charge on one atom and a partial negative charge on the other. This unequal sharing of electrons contributes to the polarity of a molecule.

41 . Which of the following molecules is polar?

a . CH4

b . CO2

c . NH3

d . O2

Answer: c. NH3.

 Explanation: NH3, or ammonia, is polar because it has a trigonal pyramidal molecular geometry, which results in a partial positive charge on the hydrogen atoms and a partial negative charge on the nitrogen atom, creating a dipole moment.

42 . Which of the following molecules has a bent molecular geometry?

a . H2O

b . CO2

c . NH3

d . CH4

Answer: a. H2O.

Explanation: H2O has a bent molecular geometry due to the two lone pairs of electrons on the oxygen atom, resulting in a tetrahedral shape with a bent bond angle.

43 . Which of the following molecules has a nonpolar covalent bond?

a . H2O

b . NH3

c . CO2

d . HCl

Answer: c. CO2.

Explanation: CO2 has a nonpolar covalent bond because the two oxygen atoms have the same electronegativity, resulting in equal sharing of electrons and no dipole moment.

44 . Which of the following molecules has a trigonal bipyramidal molecular geometry?

a . PCl3

b . SF6

c . H2O

d . CO2

Answer: b. SF6.

Explanation: SF6 has a trigonal bipyramidal molecular geometry due to the six surrounding fluorine atoms, which are arranged in a trigonal bipyramidal shape around the central sulfur atom.

45 .Which of the following molecules has a tetrahedral molecular geometry?

a . NH3

b . CO2

c . H2O

d . CH4

Answer: d. CH4.

 Explanation: CH4 has a tetrahedral molecular geometry because it has four bonding pairs of electrons around the central carbon atom, resulting in a tetrahedral shape with bond angles of 109.5 degrees.

46 . Which of the following molecules has a linear electron pair geometry?

a . H2O

b . NH3

c . CO2

d . CH4

Answer: c. CO2.

Explanation: CO2 has a linear electron pair geometry because the two oxygen atoms are on opposite sides of the carbon atom and are bonded to it through double bonds, resulting in a linear shape.

47 . Which of the following statements is true about the VSEPR theory?

a . The VSEPR theory predicts the electron pair geometry of a molecule.

b . The VSEPR theory is only applicable to molecules with covalent bonds.

c . The VSEPR theory is not applicable to molecules with lone pairs of electrons.

d . The VSEPR theory is based on the assumption that electron pairs repel each other.

Answer: d. The VSEPR theory is based on the assumption that electron pairs repel each other.

Explanation: The VSEPR theory predicts the molecular geometry of a molecule based on the repulsion between electron pairs, whether they are bonding pairs or lone pairs. It is applicable to molecules with both covalent and polar covalent bonds.

48 . Which of the following molecules has a square planar molecular geometry?

a . PF3

b . SF4

c . XeF4

d . CH4

Answer: c. XeF4.

Explanation: XeF4 has a square planar molecular geometry due to the four surrounding fluorine atoms and two lone pairs of electrons, which are arranged in a square planar shape around the central xenon atom.

49 . Which of the following molecules has a bent molecular geometry?

a . CO2

b . SO2

c . CH4

d . PF5

Answer: b. SO2.

Explanation: SO2 has a bent molecular geometry due to the lone pairs of electrons on the central sulfur atom, which repel the bonding pairs and cause a bent shape with bond angles of about 120 degrees.

50 . Which of the following statements is true about covalent bonds?

a . Covalent bonds always involve the transfer of electrons between atoms.

b . Covalent bonds are stronger than ionic bonds.

c . Covalent bonds occur between a metal and a nonmetal atom.

d . Covalent bonds involve the sharing of electrons between two atoms.

Answer: d. Covalent bonds involve the sharing of electrons between two atoms.

 Explanation: Covalent bonds occur when two atoms share electrons in order to form a stable molecule. Covalent bonds can be polar or nonpolar and are typically weaker than ionic bonds. They occur between two nonmetal atoms.

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